열처리 온도에 따른 NdFeB계 자석의 탈자 및 분별 연구
Abstract
In this study, demagnetization heat treatment conditions were studied for recycling and reuse of waste NdFeB magnets. The specimens used four different Nd magnets of N, H, UH and AH grades. To investigate the heat treatment conditions of a Nd magnet, a thermal flow computational simulation was performed to determine the exact temperature change of the magnet specimen according to the heat treatment time change at an ambient temperature inside a heat treatment furnace. It was determined that the content of elements existing inside the magnet, such as expensive heavy rare earths Dy and Tb, could be predicted by examining the rate of decrease in magnetic flux density at each heat treatment temperature.
Keywords:
Recycling, Demagnetization, Classification, NdFeB, Magnet, Heat treatmentAcknowledgments
이 논문은 2020년도 에너지기술개발사업 과제번호 20205210100070의 연구비지원으로 수행되었습니다.
References
- Jo, J. H., 2015, The Study on Activation of Resource Recycling Through Flow Analysis of Neodymium-Based Rare Earth Magnets, J. Korea Soc. Waste Manag., 32:5 500-508. [https://doi.org/10.9786/kswm.2015.32.5.500]
- Cha, H., Baek, Y., Kim, D., Lee, J., 2019, Replacing Rare- Earth Elements in Permanent Magnets, Physics and High Technology, 28:9 24-31. [https://doi.org/10.3938/PhiT.28.036]
- Oh, S., Kim, D., Gong, G., Heo, Y., Kim, J., Lee, J., 2017, Inward Diffusion of Tb Ions and the Magnetic Properties of the Nd-Fe-B Magnets, J. Korean Inst. Electr. Electron. Mater. Eng., 30:1 27-31. [https://doi.org/10.4313/JKEM.2017.30.1.27]
- Kim, S. H., Kim, J. W., Byun, J. M., Kim, D. Y., 2015, Enhancemnet of Coercivity for Nd-Fe-B Sintered Magnets, J. Korean Powder Metall. Inst., 22:1 60-67. [https://doi.org/10.4150/KPMI.2015.22.1.60]
- Kim, Y., Jung, W. S., Jeung, W. Y., 2002, Improvement of Magnetic Propertues of Nd-Fe-B Type Sintered Magnet, J. Korean Magn. Soc., 12:2 57-62. [https://doi.org/10.4283/JKMS.2002.12.2.057]
- Namkung, S., Cho, S., Kim, J., 2012, Current Satus and Research Trend of Rare-earth Permanent Magnet, J. Korean Magn. Soc., 22:6 221-227. [https://doi.org/10.4283/JKMS.2012.22.6.221]
- Lee, J., Baek, Y., Yu, J., Choi, C., 2012, Trend in Research and Development Related to Lean Heavy Rare-earth Permanent Magnets for Next-generation Motors, J. Korean Powder Metall. Inst., 19:2 151-159. [https://doi.org/10.4150/KPMI.2012.19.2.151]
- Incropera, F. P., Dewitt, D. P., 1999, Fundamental of Heat and mass Transfer (4th), Wiley, New Jersey, USA.
- White, F. M., 1998, Fluid mechanics (4th), McGraw-Hill Higher Education, New York, USA.
- Shin, H. J., Park, G. W., 2019, CFD Analysis of a 2-Stage Air Compressor for a Hydrogen Electric Car, J. Korean Soc. Manuf. Technol. Eng., 28:6 453-459. [https://doi.org/10.7735/ksmte.2019.28.6.453]
- Mazilkin, A., Straumal, B. B., Protasova, S. G., Gorji, S., Straumal, A. B., Katter, M., Schutz, G., Barezky, B., 2021, Grain Boundary Oxide Layers in NdFeB-based Permanent Magnets, Mater. Des., 199:1 1-11. [https://doi.org/10.1016/j.matdes.2020.109417]
- Haavisto, M., Tuominen, S., Kankaanpaa, H., Paju, M., 2010, Time Dependence of Demagnetization and Flux Losses Occurring in Sintered Nd-fe-B Permanent Magnets, IEEE T. Magn., 46:9 3582-3584. [https://doi.org/10.1109/TMAG.2010.2047262]
- Haavisto, M., Tuominen, S., Santa-Nokki, T., Kankaanpaa, H., Paju, M., Ruuskanen, P., 2014, Magnetic Behavior of Sintered NdFeB Magnets on a Long-Term Timescale, Advance in Materials Science and Engineering, Adv. Mater. Sci. Eng., 2014 1-7. [https://doi.org/10.1155/2014/760584]
Master Candidate in the Graduate School of NIDE Fusing Technology, Seoul National University of Science and Technology.His research interest is Material and Nano-Micro Technology.
E-mail: kbj1020@naver.com
Professor in the Department of Mechanical & Automotive Engineering, Seoul National University of Science and Technology.His Research interest is Nondestructive Evaluation.
E-mail: ikpark@seoultech.ac.kr
Professor in the NDT Research Center, Seoul National University of Science and Technology.His research interest in Material and Nano-Micro Technology.
E-mail: youngsk@seoultech.ac.kr