
전자빔 조사를 통한 고분자 표면 특성변화
Abstract
Recently, polymer surface modification has been conducted to enhance function and properties. In this study, the effect of electron beam irradiation on surface properties, such as wettability, chemical bonding state, surface roughness, hardness, critical load, and friction coefficient, of polymer coating was investigated. The polymer coating was bombarded with an intense electron beam under incident energies of 300, 600, and 900 eV for 5 min. The electron beam irradiation results showed that the contact angle was reduced as the surface converted to hydrophilic due to the formation of the carboxyl (-COOH) group. In addition, surface hardness and critical load was improved by increasing the crosslink in the polymer by electron beam irradiation.
Keywords:
Polymer, Electron beam irradiation, Wettability, Binding energy, Root mean squareAcknowledgments
본 연구는 2020년도 국가혁신클러스터 R&D 사업 “금형 코팅 기술을 적용한 생산성 향상 하드타입 크래시패드 개발” 지원을 받아 수행된 연구임(P0006666).
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Graduate Student in the School of Materials Science and Engineering, University of Ulsan.His research interest is electron beam irradiation and PVD.
E-mail: tngus2023@ulsan.ac.kr
Researcher in the Dongnam Division, Korea Institute of Industrial Technology.His research interest is PVD and PACVD coatings.
E-mail: hsb85@kitech.re.kr
Undergraduate Student in the School of Materials Science and Engineering, University of Ulsan.His research interest is electron beam irradiation and flexible TCO thin films.
E-mail: znfgn8@naver.com
Undergraduate Student in the School of Materials Science and Engineering, University of Ulsan.His research interest is surface modification and TCO thin films.
E-mail: asf724@naver.com
General Manager in the Department of Design at KBI Dongkook Ind. Co., Ltd.His research interest is injection molding.
E-mail: ksk@dkdsn.com
General Manager in the Department of Design at KBI Dongkook Ind. Co., Ltd.His research interest is component design.
E-mail: cdh@dkdsn.com
Director at KBI Dongkook Ind. Co., Ltd.His research interest is manufacturing process.
E-mail: sdi@dkdsn.com
Professor in the School of Materials Science and Engineering, University of Ulsan.His research interest is PVD and TCO thin films.
E-mail: dkim84@ulsan.ac.kr